Optimization of Parameters for Purification of Jatropha Curcas Based Biodiesel using Organic Adsorbents

Sangita Banga, Pradeep Varshney, Naveen Kumar, Madan Pal

Abstract


This paper discusses purification of biodiesel by using organic adsorbents instead of traditional water washing technique. The efficiency of different organic adsorbents under different conditions was compared with each other as well as traditional water washed biodiesel for the purification of Jatropha Curcas based transesterified biodiesel. The proposed methodologies were based on the use of Amberlite BD10 DRY, Purolite PD 206 and Tulison T-45BD as adsorbents. The response of each adsorbent was measured through the determination of all the potential impurities like, free alkali, residual alcohol, moisture content, soap content and free and bonded glycerol; present in the biodiesel as per ASTM/EN Standard test method. As a result, it is observed that increasing the temperature from room temperature to 65° C decreases the time of contact as well as the amount of adsorbent required for the removal of impurities. On comparing the results of conventional acid water washing with that of organic adsorbents (at 3% (w/w) concentration with stirring time 25 min at 65°C), these matrices are found to be equally appropriate for the removal of contaminant species from biodiesel. The values for free potassium, residual methanol and free and bonded glycerol are found within the EN 14214 maximum limits.


Keywords


biodiesel; dry wash; Amberlite BD-10 Dry; Purolite PD-206; Tulison T-45BD

Full Text:

PDF

References


Pramanik K.. Properties and use of Jatropha curcas oil and diesel fuel blends in compression ignition engine. Renewable Energy 2: 239-48, 2003.

Shah S., Sharma A. and Guptha MN. Extraction of oil from Jatropha curcas L. seed kernels by enzyme assisted three phase partitioning. Industrial crops and products 20: 275-79, 2004.

Tiwari A.K., Kumar A. and Raheman H. Biodiesel production from Jatropha oil (Jatropha curcas) with high free fatty acids: An optimized process. Biomass Bioenergy 31: 569-75, 2007.

Berchmans H.J.and Hirata S. Biodiesel production from crude Jatropha curcas L. seed oil with a high content of free fatty acids. Bioresource Technology 99: 1716-21, 2008.

Akbar E., Yaakob Z., Kamarudin S.K., Ismail M. and Salimon J. Characteristic and Composition of Jatropha Curcas Oil seed from Malaysia and its potential as biodiesel feedstock, European Journal of Scientific Research 29:396-03, 2009.

Crabbe E., Nolasco Hipolito C.N., Kobayashi G., Sonomoto K. and Ishizaki A. Biodiesel production from crude palm oil and evaluation of butanol extraction and fuel properties. Process Biochemistry 37: 65-71, 2001.

B. Freedman, E.H. Pryde and T.L. Mounts. Variables affecting the yields of fatty acid esters from transesterifred vegetable oils. Journal of American Oil Chemical Society 61:1638-43,1984.

M. Mittelbach, B. Pokits and A. Silberholz. Diesel fuel derived from vegetable oils, IV: Production and fuel properties of fatty acid methyl esters from used frying oil. Liquid fuels from renewable resources. Proceedings of the alternative energy conference, Michigan (USA): American Society of Agricultural Engineers Page No. 74, 1994.

L. Yingying, L. Houfang and L. Bin. Effect of water on the pre esterification of Jatropha curcas L. Oil for biodiesel production. Journal of Biobased Materials and Bioenergy 3: 342-47, 2009.

J.Y. Park, Z.M. Wang, D.K. Kim and J.S. Lee. Effects of water on the esterification of free fatty acids by acid catalysts. Renewable Energy 35: 614-18, 2010.

Yori, J. C., D'Ippolito, S. A., Pieck, C. L. and Vera, C. R. Deglycerolization of biodiesel streams by adsorption over silica beds. Energy Fuels 21:347-53, 2007.

Bondioli, P. and Bella, L. D. An Alternative Spectrophotometric Method for the Determination of Free Glycerol in Biodiesel. European Journal of Lipid Science Technology 107:153-5, 2005.

Mittelbach, M. Diesel fuel derived from vegetable oils, VI: Specifications and quality control of biodiesel. Bioresource Technology 56:7-11, 1996.

Predojevic, Z. J. The production of biodiesel from waste frying oils: a comparison of different purification steps. Fuel 87: 3522-28, 2008.

Hajimahmoodi, M., Heyden, Y. V., Sadeghi, N., Jannat, B., Oveisi, M. R. and Shahbazian, S. Gas-chromatographic fatty-acid fingerprints and partial least squares modeling as a basis for the simultaneous determination of edible oil mixtures. Talanta 66:1108-16, 2005) .

Joshi, R. M. and Pegg, M. J. Flow properties of biodiesel fuel blends at low temperatures. Fuel 86:143-51, 2007.

Zhou, W. Y.and Boocock, D. G. B. Phase behavior of the base catalyzed transesterification of soybean oil. Journal of American Oil Chemical Society 83:1041-45, 2006.

Maria M. Bubble, Washing biodiesel and dealing with wash problems, http://www.biodieselcommunity.org

Bryan T.; Biodiesel Magazine http://www.biodieselmagazine.com , March 2005.

Cooke, B. S. Abrams, C. and Bertram, B. Purification of biodiesel with adsorbent materials US Patent 0509959P, 2003.

Kucek, K. T., César-Oliveira, M. A. T., Wilhelm, M. H. and Ramos, L. Ethanolysis of Refined Soybean Oil Assisted by Sodium and Potassium Hydroxides. Journal of American Oil Chemical Society 84: 385-92, 2007.

Karaosmanoglu, F., Cigizoglu, K. B., Tuter, M. and Ertekin, S. Investigation of the refining step of biodiesel production. Energy Fuels 10: 890-95, 1996.

Jacob Wall and Jon Van Grepen. Comparison of methods for the purification of Biodiesel. Thesis Presented in partial fulfillment of the requirements for the degree of master of science, University of Idaho, 2009.

Candice Schmitt Faccini. Dry washing in biodiesel purification: a comparative study of adsorbents. Journal of the Brazilian Chemical Society 22: 558-63, 2011.




DOI (PDF): https://doi.org/10.20508/ijrer.v4i3.1349.g6412

Refbacks

  • There are currently no refbacks.


Online ISSN: 1309-0127

Publisher: Gazi University

IJRER is cited in SCOPUS, EBSCO, WEB of SCIENCE (Clarivate Analytics);

IJRER has been cited in Emerging Sources Citation Index from 2016 in web of science.

WEB of SCIENCE between 2020-2022; 

h=30,

Average citation per item=5.73

Impact Factor=(1638+1731+1808)/(189+170+221)=9.24

Category Quartile:Q4